Although set b [expr $a * 4] is correct, a more efficient way of doing the same is set b [expr {$a * 4}]. This will speed up the operation as the compiler works on the latter method better.
Double-quotes allow you to specify words that contain spaces
Curly braces provide another way of grouping information into words.
They are different from quotes in that no substitutions are performed on the text between the curly braces