The \xampp\apache\bin\php.ini is the correct one! The others in the \xampp\php directory are only for PHP in CGI/CLI mode. So configure the \xampp\apache\bin\php.ini for web changes.
Modifications in the php.ini will be saved also after the "PHP switch" (the changing of the PHP version). And note: Modifications in the php.ini and in the httpd.conf always need a Apache restart!
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