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Preheat the oven to 350F.
In a food processor, whiz the sugar and vanilla bean for several minutes until the vanilla is in tiny flecks.
Meanwhile, melt the butter over low heat in a large saucepan. Add the chocolate and stir until melted. Whisk in the vanilla and eggs, then the sugar mixture, salt, flour and nuts.
Transfer the batter to a well-greased 8x8 cake pan and smooth the surface. Bake for 30 – 40 minutes or until a knife inserted in the center comes out clean. Cool and cut into 16 squares. If desired, sprinkle with powdered sugar.
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